Issue 97, 2019
From the journal:

Chemical Communications

Reversible pyrrole-based proton storage/release in ruthenium(ii) complexes†

Zheng-Hao Zhang,a   Piao He, ORCID logo a   Shi-Rui Kang,a   Chao Liua  and  Xiao-Yi Yi ORCID logo *a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan 410083, China
E-mail: xyyi@csu.edu.cn

Abstract

Newly designed ruthenium(II) complexes are reported which contain a pyridylpyrrole ligand featuring fast-responsive and reversible proton storage/release on the pyrrole group. The protonated pyrrolium acts as an acidic initiator and is capable of triggering the polymerization of 2,2-dimethyloxirane.

Graphical abstract: Reversible pyrrole-based proton storage/release in ruthenium(ii) complexes

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Article information

DOI
https://doi.org/10.1039/C9CC08288C
Article type
Communication
Submitted
22 Oct 2019
Accepted
05 Nov 2019
First published
06 Nov 2019

Chem. Commun., 2019,55, 14594-14597

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Reversible pyrrole-based proton storage/release in ruthenium(II) complexes

Z. Zhang, P. He, S. Kang, C. Liu and X. Yi, Chem. Commun., 2019, 55, 14594 DOI: 10.1039/C9CC08288C

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