A two-dimensional perovskite incorporating an amine moiety with a carboxyl group exhibited variations in orientation with changes in the ambient humidity. It was possible to increase the degree of vertical orientation by optimizing the film thickness and promoting crystallization at the interface between the film and the film-forming atmosphere.
R. Arai, M. Yoshizawa-Fujita, Y. Takeoka and M. Rikukawa, CrystEngComm, 2019, 21, 4529 DOI: 10.1039/C9CE00631A
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