Issue 28, 2019

An efficient approach to modulate the coordination number of yttrium ions for diverse network formation

Abstract

Yttrium-based MOFs with different coordination numbers (CNs) of yttrium ions were synthesized from the same precursor. The 7-coordinated yttrium-based MOF exhibits an infinite 3D structure, while the 9-coordinated yttrium-based MOF shows a 2D layer stacked structure. Control experiments showed that the concentration of the ligand determines the CN and eventually the geometric structures.

Graphical abstract: An efficient approach to modulate the coordination number of yttrium ions for diverse network formation

Supplementary files

Article information

Article type
Communication
Submitted
03 May 2019
Accepted
10 Jun 2019
First published
18 Jun 2019

CrystEngComm, 2019,21, 4136-4140

An efficient approach to modulate the coordination number of yttrium ions for diverse network formation

J. Park, J. Y. Koo and H. C. Choi, CrystEngComm, 2019, 21, 4136 DOI: 10.1039/C9CE00676A

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