Trinuclear Ni(II) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation

Zhi-Min Zhai; Xiao-Gang Yang; Zhao-Tong Yang; Xiao-Min Lu; Lu-Fang Ma

doi:10.1039/C9CE00944B

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Trinuclear Ni(ii) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation†

Zhi-Min Zhai,^ab Xiao-Gang Yang,

*^b Zhao-Tong Yang,^b Xiao-Min Lu^b and Lu-Fang Ma

^ab

Author affiliations

* Corresponding authors

^a College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China

^b College of Chemistry and Chemical Engineering, Henan Province Function-Oriented Porous Materials Key Laboratory, Luoyang Normal University, Luoyang 471934, P. R. China
E-mail: yxg2233@126.com

Abstract

Oriented by the structure-directing effect of metal clusters, a novel trinuclear nickel-based MOF (Ni–BTC) exhibited highly denser crystal packing and π-conjugation degree, providing a platform for efficient charge carrier mobility between metal clusters through π-conjugated molecular bridges and long-term stability of an efficient oxygen evolution reaction.

This article is part of the themed collection: Editors collection: Metal Organic Frameworks as catalysts for water splitting and CO2 reduction

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Article information

DOI: https://doi.org/10.1039/C9CE00944B
Article type: Communication
Submitted: 18 Jun 2019
Accepted: 02 Sep 2019
First published: 03 Sep 2019

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CrystEngComm, 2019,21, 5862-5866

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Trinuclear Ni(II) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation

Z. Zhai, X. Yang, Z. Yang, X. Lu and L. Ma, CrystEngComm, 2019, 21, 5862 DOI: 10.1039/C9CE00944B

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Trinuclear Ni(ii) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation†

Abstract

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Trinuclear Ni(II) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation

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