A heterometallic sodium(i)–europium(iii)-organic layer exhibiting dual-responsive luminescent sensing for nitrofuran antibiotics, Cr2O72− and MnO4− anions

Abstract

The detection of nitrofuran antibiotics and toxic inorganic anions is currently necessary and challenging because their abuse and/or residuals have caused severe environmental pollution and illness. A heterometallic two-dimensional (2D) layered complex, {[Eu₂Na(Hpddb)(pddb)₂(CH₃COO)₂]·2.5(DMA)}_n (1), was solvothermally synthesized and structurally and photophysically characterized. Pairs of acetate aggregated {Eu₂Na(CH₃COO)₂} chains are periodically interconnected by V-shaped 4,4′-(pyridine-2,6-diyl)dibenzolate (pddb) linkers. More interestingly, the layered complex exhibits a bright red emission and can efficiently discriminate nitrofuran antibiotics by luminescent quenching with a strong quenching constant (K_sv) and low detection limit (LOD) of 4.93 × 10⁴ M⁻¹ and 0.64 μM for nitrofurazone, 4.42 × 10⁴ M⁻¹ and 0.68 μM for nitrofurantoin as well as 2.13 × 10⁴ M⁻¹ and 1.06 μM for furazolidone. Additionally, 1 can also probe trace amounts of toxic Cr₂O₇²⁻ and MnO₄⁻ anions with K_sv = 6.45 × 10³ M⁻¹ and LOD = 5.35 μM for Cr₂O₇²⁻ and K_sv = 2.84 × 10³ M⁻¹ and LOD = 5.99 μM for MnO₄⁻ anions. These interesting results indicate that heteromatallic coordination polymers can serve as favorable dual- or even multiple-responsive luminescence sensors to selectively recognize different kinds of contaminants.