Issue 4, 2019
From the journal:

Dalton Transactions

Bis(bipyridine) ruthenium(ii) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation†

Shin Takemoto, ORCID logo *a   Manami Kitamura,a   Shuhei Saruwatari,a   Atsutaka Isono,a   Yoko Takada,a   Rie Nishimori,a   Mina Tsujiwaki,a   Naoki Sakauea  and  Hiroyuki Matsuzaka ORCID logo a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
E-mail: takemoto@c.s.osakafu-u.ac.jp

Abstract

The first phosphido derivative of the bis(bipyridine) ruthenium(II) fragment, cis-[(bpy)2Ru(PPh2)2] ([RuP2]), has been developed and applied as a P-donor metalloligand to form new Ru–Rh, Ru–Ir and Ru2Cu2 heterometallic complexes. The Ru–Ir hydride complex [([RuP2])IrH(NCMe)3][BF4]2 exhibits significant catalytic activity for (E)-selective semi-hydrogenation of alkynes.

Graphical abstract: Bis(bipyridine) ruthenium(ii) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8DT04646H
Article type
Communication
Submitted
23 Nov 2018
Accepted
07 Dec 2018
First published
07 Dec 2018

Dalton Trans., 2019,48, 1161-1165

Permissions

Request permissions

Bis(bipyridine) ruthenium(II) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation

S. Takemoto, M. Kitamura, S. Saruwatari, A. Isono, Y. Takada, R. Nishimori, M. Tsujiwaki, N. Sakaue and H. Matsuzaka, Dalton Trans., 2019, 48, 1161 DOI: 10.1039/C8DT04646H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements