Issue 13, 2019

Ge(ii) cation catalyzed hydroboration of aldehydes and ketones

Abstract

Well-defined germylene cations [(i-Bu)2ATI]GeOTf (4) and [(i-Bu)2ATIGe][GaCl4] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate).

Graphical abstract: Ge(ii) cation catalyzed hydroboration of aldehydes and ketones

Supplementary files

Article information

Article type
Communication
Submitted
26 Dec 2018
Accepted
07 Feb 2019
First published
07 Feb 2019

Dalton Trans., 2019,48, 4094-4100

Ge(II) cation catalyzed hydroboration of aldehydes and ketones

S. Sinhababu, D. Singh, M. K. Sharma, R. K. Siwatch, P. Mahawar and S. Nagendran, Dalton Trans., 2019, 48, 4094 DOI: 10.1039/C8DT05121F

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