Issue 13, 2019
From the journal:

Dalton Transactions

Strapping a benzaldehyde-appended 2,2′-bis-dipyrrin Zn(ii) double-stranded helicate using imine bond formation†

Fan Zhang, ORCID logo a   Audrey Fluck, ORCID logo a   Stéphane A. Baudron ORCID logo *a  and  Mir Wais Hosseini ORCID logo *a  

* Corresponding authors

a Laboratoire de Tectonique Moléculaire, UMR CNRS 7140, icFRC, Université de Strasbourg, Strasbourg, France
E-mail: sbaudron@unistra.fr, hosseini@unistra.fr
Fax: +33 368851325
Tel: +33 368851323

Abstract

A novel linear binuclear Zn(II)/2,2′-bis-dipyrrin double-stranded helicate bearing peripheral p-benzaldehyde moieties has been strapped by formation of imine bonds upon reaction with m-xylylenediamine and characterized by 1H- and 13C-NMR spectroscopy, UV-Visible spectroscopy and high-resolution mass spectrometry.

Graphical abstract: Strapping a benzaldehyde-appended 2,2′-bis-dipyrrin Zn(ii) double-stranded helicate using imine bond formation

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Article information

DOI
https://doi.org/10.1039/C9DT00377K
Article type
Communication
Submitted
27 Jan 2019
Accepted
20 Feb 2019
First published
21 Feb 2019

Dalton Trans., 2019,48, 4105-4108

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Strapping a benzaldehyde-appended 2,2′-bis-dipyrrin Zn(II) double-stranded helicate using imine bond formation

F. Zhang, A. Fluck, S. A. Baudron and M. W. Hosseini, Dalton Trans., 2019, 48, 4105 DOI: 10.1039/C9DT00377K

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