Synthesis and molecular structure of enantiomerically pure pentadienyl complexes of the rare-earth metals

Abstract

The enantiomerically pure pentadienyl (Pdl*) ligand derived from the natural product (1R)-(−)-myrtenal forms with MCl₃ (M = La, Ce, Pr, and Nd) the corresponding homoleptic [(η⁵-U-Pdl*)₃M compounds (1-M). These complexes were fully characterised by ¹H NMR spectroscopy, elemental analyses and X-ray diffraction. They exhibit in solution and solid state idealized C₃ symmetry, and their molecular structures also reveal that the Pdl* ligand adopts a U-conformation and coordinates exclusively with its less sterically encumbered face to the rare-earth metal atom. For the paramagnetic representatives an assignment of the ¹H NMR resonances based on a simple dipolar model gave satisfactory results.