Issue 27, 2019
From the journal:

Dalton Transactions

Designed synthesis of a proton-conductive Ho-MOF with reversible dehydration and hydration†

Sa-Sa Wang, ORCID logo a   Xiao-Yuan Wu, ORCID logo a   Zhong Lib  and  Can-Zhong Lu ORCID logo *a  

* Corresponding authors

a CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: czlu@fjirsm.ac.cn

b State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou, Fujian, China

Abstract

A Ho-MOF ([Ho(SIP)(H2O)5]·3H2O (1), NaH2SIP = monosodium 5-sulfoisophthalic acid) was designed and synthesized for proton conductivity. It showed a proton conductivity of 8.2 × 10−4 S cm−1 at 343 K and 98% relative humidity. Besides, compound 1 showed excellent water and chemical stability as well as reversible dehydration and hydration closely related to the proton conductivity.

Graphical abstract: Designed synthesis of a proton-conductive Ho-MOF with reversible dehydration and hydration

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Article information

DOI
https://doi.org/10.1039/C9DT02269D
Article type
Communication
Submitted
29 May 2019
Accepted
30 May 2019
First published
14 Jun 2019

Dalton Trans., 2019,48, 9930-9934

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Designed synthesis of a proton-conductive Ho-MOF with reversible dehydration and hydration

S. Wang, X. Wu, Z. Li and C. Lu, Dalton Trans., 2019, 48, 9930 DOI: 10.1039/C9DT02269D

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