Recent advances in understanding Li–CO2 electrochemistry

Abstract

With ever-increasing demand for balancing CO₂ emissions and maximizing electrical energy supplies, Li–CO₂ electrochemistry, coupled with dual characteristics of advanced energy storage and effective CO₂ fixation, has been attracting considerable attention from researchers. Herein, we offer a real-time, in-depth, and overall review of the latest research progress concerning CO₂ reduction/evolution reaction mechanisms in Li–CO₂/O₂ and Li–CO₂ electrochemical systems. Meanwhile, affecting factors on the reaction pathways and the identification of discharge products are summarized and discussed. Then, Li anode/electrolyte interface construction, electrolyte properties and selection of cathode materials/catalysts and design strategy, especially their effect on the performance of Li–CO₂/O₂ and Li–CO₂ batteries, are explored and possible solutions and suggestions are provided. Building on an in-depth understanding of Li–CO₂ electrochemistry, novel flexible Li–CO₂ batteries and key factors are summarized. Furthermore, based on advanced research progress in the past several years, we identify the main problems, controversies, and challenges currently existing in various battery components that remain to be addressed to design more practicable Li–CO₂/O₂ and Li–CO₂ batteries. Finally, future research directions and opportunities are presented.