Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

Rinish Reddy Vaidyula; Pierre-Yves Dugas; Eleanor Rawstron; Elodie Bourgeat-Lami; Damien Montarnal

doi:10.1039/C9PY00644C

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Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants†

Rinish Reddy Vaidyula,^a Pierre-Yves Dugas,

^a Eleanor Rawstron,^a Elodie Bourgeat-Lami

*^a and Damien Montarnal

*^a

Author affiliations

* Corresponding authors

^a Univ Lyon. Université Claude Bernard Lyon 1, CPE Lyon, CNRS, UMR 5265, Chemistry, Catalysis, Polymers and Processes, 43 Bvd du 11 Novembre 1918, F-69616 Villeurbanne, France
E-mail: damien.montarnal@univ-lyon1.fr, elodie.bourgeat-lami@univ-lyon1.fr

Abstract

Epoxy-acid vitrimer particles with excellent osmotic and hydrolytic stability were synthesized by miniemulsion polymerization thanks to in situ generation of surfactants from the carboxylic acid reagent and a water-soluble base. The sulfate-free vitrimers formed in this way show greatly reduced creep viscosities.

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Article information

DOI: https://doi.org/10.1039/C9PY00644C
Article type: Communication
Submitted: 02 May 2019
Accepted: 10 May 2019
First published: 13 May 2019

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Polym. Chem., 2019,10, 3001-3005

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Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

R. R. Vaidyula, P. Dugas, E. Rawstron, E. Bourgeat-Lami and D. Montarnal, Polym. Chem., 2019, 10, 3001 DOI: 10.1039/C9PY00644C

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Polymer Chemistry

Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants†

Abstract

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Improved malleability of miniemulsion-based vitrimers through in situ generation of carboxylate surfactants

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