Issue 19, 2019

A free-radical-promoted stereospecific denitro silylation of β-nitroalkenes with silanes

Abstract

A Cu-catalyzed stereospecific denitro silylation of β-nitroalkenes with silanes for the synthesis of vinylsilanes using DTBP as the oxidant was developed. This method presented an inexpensive and non-toxic catalytic system with an appropriate substrate scope. This approach is (E)-specific and produced an important class of vinylsilanes in good yields.

Graphical abstract: A free-radical-promoted stereospecific denitro silylation of β-nitroalkenes with silanes

Supplementary files

Article information

Article type
Research Article
Submitted
27 Jun 2019
Accepted
14 Aug 2019
First published
21 Aug 2019

Org. Chem. Front., 2019,6, 3365-3368

A free-radical-promoted stereospecific denitro silylation of β-nitroalkenes with silanes

X. Zhang, M. Liu, T. Wang, Y. Wang, X. Wang and Z. Quan, Org. Chem. Front., 2019, 6, 3365 DOI: 10.1039/C9QO00819E

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