Free-standing polypyrrole/polyaniline composite film fabricated by interfacial polymerization at the vapor/liquid interface for enhanced hexavalent chromium adsorption

Abstract

Interfacial polymerization is an innovative technique for the fabrication of polymeric films. However, the majority of studies on interfacial polymerization has focused on liquid/liquid interfaces, and little work has been done on vapor/liquid interfaces. In this paper, we present the fabrication of free-standing polypyrrole/polyaniline (PPy/PANI) composite films by interfacial polymerization at a vapor/liquid interface using FeCl₃ as an oxidant. The obtained PPy/PANI composite films were characterized using Fourier transform infrared spectroscopy, X-ray diffractometry, and scanning electron microscopy. It was found that the PPy/PANI composite films consist of PANI particles evenly distributed on porous PPy film. The influence of FeCl₃ concentration on the morphology of the resulting composite films was investigated. The PPy/PANI composite films show an excellent Cr(VI) adsorption capacity of 256.41 mg g⁻¹, much higher than that of PPy-based absorbents prepared from chemical and electrochemical polymerization routes. This work thus suggests a new route for the fabrication of PPy/PANI films with highly enhanced Cr(VI) adsorption capacity for practical applications.