Issue 15, 2019, Issue in Progress

Phenanthroline-based microporous organic polymer as a platform for an immobilized palladium catalyst for organic transformations

Abstract

Porous organic polymers have attracted significant attention owing to their large specific surface area, excellent chemical and thermal stability, and controllable skeletons. phenanthroline-based microporous organic polymer (Phen-MOP) has been synthesized via a cost-effective method based on the Scholl reaction. The Phen-MOP polymer exhibits high surface area and good stability. Owing to the phenanthroline skeleton embedding into the microporous polymer framework, the Phen-MOP can serve as a platform to support a transition metal catalyst. After being post-modified with palladium acetate, the synthesized Phen-Pd-MOP framework can serve as a highly efficient heterogeneous catalyst for the Suzuki–Miyaura coupling reaction and the Heck coupling reaction. Moreover, the Phen-Pd-MOP catalyst could be reused at least 10–12 times without any significant loss of the catalytic activity.

Graphical abstract: Phenanthroline-based microporous organic polymer as a platform for an immobilized palladium catalyst for organic transformations

Supplementary files

Article information

Article type
Paper
Submitted
18 Jan 2019
Accepted
27 Feb 2019
First published
13 Mar 2019
This article is Open Access
Creative Commons BY license

RSC Adv., 2019,9, 8239-8245

Phenanthroline-based microporous organic polymer as a platform for an immobilized palladium catalyst for organic transformations

C. Wang, K. Nie, G. Song, Y. Li and Y. Han, RSC Adv., 2019, 9, 8239 DOI: 10.1039/C9RA00460B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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