Solvent-free incorporation of CO2 into 2-oxazolidinones: a review

Abstract

This review is an attempt to give an overview on the recent advances and developments in the synthesis of 2-oxazolidinone frameworks through carbon dioxide (CO₂) fixation reactions under solvent-free conditions. The cycloaddition of CO₂ to aziridine derivatives is discussed first. This is followed by carboxylative cyclization of N-propargylamines with CO₂ and three-component coupling of epoxides, amines, and CO₂. Finally, cycloaddition of CO₂ to propargylic alcohols and amines will be covered at the end of the review. The literature has been surveyed up until the end of 2018.