Homologous–heterogeneous structure control and intelligent adsorption effect of a polycationic gel for super-efficient purification of dyeing wastewater

Abstract

A homologous–heterogeneous polycationic gel (HPCG) system was constructed by a waste-free synthesis process, to be used as a super-efficient adsorbent material for purifying dyeing wastewater. It is the first discovery of a new intelligent adsorption effect occurring in HPCG adsorption by detecting the homologous–heterogeneous structure transformations in HPCG adsorption using optical microscopy, scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy analysis technologies. The adsorption capacities of HPCG products were 532.55–605.45 times higher than that of the widely-used activated carbon, thereby being the greatest improvement of the adsorption ability for HPCG versus this existing adsorbent. Meanwhile, the adsorption capacities of HPCG were also improved by 3.67–46.05 times compared to that of all the similar polycationic cotton adsorbents reported in our previous serial works, demonstrating more efficient purification of dyeing wastewater than we could do before. In addition, through studying the adsorption models, it was further discovered that HPCG adsorption followed the new two-segment adsorption process, i.e. including a speed control segment and an acceleration segment, also confirming the existence of the intelligent adsorption effect for HPCG adsorption.