High pairing rate Janus-structured microfibers and array: high-efficiency conjugate electrospinning fabrication, structure analysis and co-instantaneous multifunctionality of anisotropic conduction, magnetism and enhanced red fluorescence

Abstract

A highly efficient and convenient conjugate electrospinning technique is employed to obtain high pairing rate Janus-structured microfibers in electrospun products by optimizing the spinning conditions. In addition, a Janus-structured microfiber array rendering tri-functional performance of tunable magnetism, electrically anisotropic conduction and increased fluorescence is prepared via the same technique using a rotating device as a fiber collector. The array is composed of an ordered arrangement of Janus-structured microfibers. The extraordinary Janus structure and oriented arrangement endow the Janus-structured microfibers with excellent fluorescence. The fluorescence intensity of the Janus-structured microfiber array is, respectively, 1.21, 14.3 and 20.3 times higher than that of the Janus-structured microfiber non-array, the composite microfiber array and the composite microfiber non-array. The Janus-structured microfiber array has a similar saturation magnetization to the contradistinctive specimens. Additionally, the magnetism of the Janus-structured microfiber array can be modulated with different mass ratios of Fe₃O₄ nanoparticles (NPs), and the conductance ratio between the length direction and diameter direction of the Janus-structured microfibers for the array can be tuned from 10³ to 10⁶ by adding a higher percentage of polyaniline (PANI). Our new findings have established a highly efficient conjugate electrospinning technique to prepare Janus-structured microfibers of high pairing rate, and complete isolation of fluorescent material from magnetic nanoparticles and conductive material is accomplished in the Janus-structured microfibers to ensure high fluorescence intensity without a notably disadvantageous influence of dark-colored substances. More importantly, the fabrication technique for the Janus-structured microfibers can be generalized to manufacture other Janus-structured multifunctional materials.