Eco-friendly and facile one-step synthesis of a three dimensional net-like magnetic mesoporous carbon derived from wastepaper as a renewable adsorbent

Abstract

Millions of tons of paper and its derivatives are annually wasted without being recycled and reused. To promote the comprehensive utilization of resources and eco-friendly preparation, waste filter paper, printer paper, and napkins were chosen as carbon sources to one-step synthesize three types of three dimensional (3D) net-like magnetic mesoporous carbon (MMC) by an eco-friendly and low-cost method. These mesoporous (3.90–7.68 nm) composites have a high specific surface area (287–423 m² g⁻¹), well-developed porosity (0.24–0.74 cm³ g⁻¹) and abundant oxygen-containing functional groups. Compared to the other two composites, the adsorbent derived from filter paper showed the highest adsorption capacity towards methylene blue (MB) (q_max = 332.03 mg g⁻¹) and rhodamine B (RhB) (q_max = 389.59 mg g⁻¹) with a high adsorption rate (<5 min). According to the effect of pH value on adsorption capacity, and combining the analysis of Fourier transform infrared spectrometry and X-ray photoelectron spectroscopy, the main adsorption mechanisms can be summarized as hydrogen bonds, electrostatic interactions, and π–π interaction. Besides, the occurrence of redox reactions between Fe²⁺/Fe⁰ and dye cannot be ignored. Finally, experiments on reusability were performed. They showed that the 3D net-like MMC could be easily regenerated and still maintained a removal efficiency of above 80% for RhB and 90% for MB after five cycles.