Stable P3HT: amorphous non-fullerene solar cells with a high open-circuit voltage of 1 V and efficiency of 4%

Abstract

A non-fullerene small molecule acceptor, SF-HR composed of 3D-shaped spirobifluorene and hexyl rhodanine, was synthesized for use in bulk heterojunction organic solar cells (OSCs). It possesses harmonious molecular aggregation between the donor and acceptor, due to the interesting diagonal molecular shape of SF-HR. Furthermore, the energy level of SF-HR matches well with that of the donor polymer, poly(3-hexyl thiophene) (P3HT) in this system which can affect efficient charge transfer and transport properties. As a result, OSCs made from a P3HT:SF-HR photoactive layer exhibited a power conversion efficiency rate of 4.01% with a high V_OC of 1.00 V, a J_SC value of 8.23 mA cm⁻², and a FF value of 49%. Moreover, the P3HT:SF-HR film showed superior thermal and photo-stability to P3HT:PC₇₁BM. These results indicate that SF-HR is specialized as a non-fullerene acceptor for use in high-performance OSCs.