Facile thermochemical conversion of FeOOH nanorods to ZnFe2O4 nanorods for high-rate lithium storage

Abstract

We successfully prepared ZnFe₂O₄ nanorods (ZFO-NRs) by a simple thermochemical reaction of FeOOH nanorods with Zn(NO₃)₂ to use as an anode material in lithium-ion batteries. The FeOOH nanorod shape was well maintained after conversion into ZFO-NR with the formation of porous structures. The nanorod structure and porous morphology facilitate Li⁺ transport, improve the reaction rates owing to the larger contact area with the electrolyte, and reduce the mechanical stress during lithiation/delithiation. The ZFO-NR electrode exhibited a reversible capacity of 725 mA h g⁻¹ at 1 A g⁻¹ and maintained a capacity of 668 mA h g⁻¹ at 2 A g⁻¹; these capacities are much higher and more stable than those of ZFO nanoparticles prepared by a hydrothermal method (ZFO-HT) (216 and 117 mA h g⁻¹ at 1 and 2 A g⁻¹, respectively). Although ZFO-NRs exhibited high, stable capacities at moderate current densities for charging and discharging, the capacity rapidly decreased under fast charging/discharging conditions (>4 A g⁻¹). However, carbonized ZFO-NR (C/ZFO-NR) exhibited an improved reversible capacity and rate capability resulting from an increased conductivity compared with ZFO-NRs. The specific capacity of C/ZFO-NRs at 1 A g⁻¹ was 765 mA h g⁻¹; notably, a capacity of 680 mA h g⁻¹ was maintained at 6 A g⁻¹.