In situ self-assembly of Ni3S2/MnS/CuS/reduced graphene composite on nickel foam for high power supercapacitors

Abstract

Transition metal sulfides (TMS), as promising electroactive materials for asymmetric supercapacitors, have been limited due to their relatively poor conductivity and cycle stability. Here ternary Ni₃S₂/MnS/CuS composites were assembled in situ on nickel foam (NF) using a hydrothermal method via electrostatic adsorption of Ni⁺, Mn²⁺ and Cu²⁺ ions on a reduced graphene (rGO) nanosheet template. The chemical structure was characterized by various analytic methods. Ni₃S₂/MnS/CuS has spherical morphology assembled from closely packed nanosheets, while Ni₃S₂/MnS/CuS@rGO has a three-dimensional porous spherical structure with much lower diameter because rGO nanosheets can play the role of a template to induce the growth of Ni₃S₂/MnS/CuS. At a current density of 1 A g⁻¹, the specific capacitance was obtained to be 1028 F g⁻¹ for Ni₃S₂/MnS/CuS, 628.6 F g⁻¹ for Ni₃S₂/MnS@rGO, and 2042 F g⁻¹ for Ni₃S₂/MnS/CuS@rGO, respectively. Charge transfer resistance (R_ct) of Ni₃S₂/MnS/CuS@rGO (0.001 Ω) was much lower than that of Ni₃S₂/MnS@rGO by 0.02 Ω, and lower than that of Ni₃S₂/MnS/CuS by 0.017 Ω. After 5000 cycles, the Ni₃S₂–MnS–CuS@RGO electrode maintains 78.3% of the initial capacity at 20 A g⁻¹. An asymmetric supercapacitor was subsequently assembled using Ni₃S₂/MnS/CuS@rGO as the positive electrode and rGO as the negative electrode. The specific capacitance of asymmetric batteries was maintained at 90.8% of the initial state after 5000 GCD.