Electrospun Janus-like pellicle displays coinstantaneous tri-function of aeolotropic conduction, magnetism and luminescence

Abstract

A new Janus-like pellicle with top-bottom structure, functionalized by conductive aeolotropism, magnetism and luminescence (defined as a CML Janus-like pellicle), is conceived and constructed via electrospinning by combining microcosmic with macroscopic partitions. [PANI/PMMA]//[Eu(BA)₃phen/PMMA] and [Fe₃O₄/PMMA]//[Tb(BA)₃phen/PMMA] Janus-like microribbons are selected as building units to construct a conductive aeolotropism-luminescence layer (CL layer) and magnetism-luminescence layer (ML layer), and the two layers are combined to form a CML Janus-like pellicle. Macroscopic partition is achieved by designing the Janus-like structure of the pellicle, while Janus-like microribbons are used for the microcosmic partition by separating rare earth luminescent compounds from dark-colored magnetic Fe₃O₄ NPs and conductive PANI. The CML Janus-like pellicle has stronger luminescence compared to the contrast samples. The magnetism of the CML Janus-like pellicle can be adjusted by changing the doping amount of Fe₃O₄ NPs. The CML Janus-like pellicle can achieve a strong and variable conductive aeolotropism via changing the doping amount of PANI and the highest conductive aeolotropism ratio can reach ca. 10⁸ times when the PANI content is 70%. Microcosmic and macroscopic partitions are simultaneously integrated into the CML Janus-like pellicle, which results in almost no detrimental mutual influences between the two layers, and the overall performances of the CML Janus-like pellicle are greatly improved.