g-C3N4/CuO and g-C3N4/Co3O4 nanohybrid structures as efficient electrode materials in symmetric supercapacitors

Abstract

Metal oxide dispersed graphitic carbon nitride hybrid nanocomposites (g-C₃N₄/CuO and g-C₃N₄/Co₃O₄) were prepared via a direct precipitation method. The materials were used as an electrode material in symmetric supercapacitors. The g-C₃N₄/Co₃O₄ electrode based device exhibited a specific capacitance of 201 F g⁻¹ which is substantially higher than those using g-C₃N₄/CuO (95 F g⁻¹) and bare g-C₃N₄ electrodes (72 F g⁻¹). At a constant power density of 1 kW kg⁻¹, the energy density given by g-C₃N₄/Co₃O₄ and g-C₃N₄/CuO devices is 27.9 W h kg⁻¹ and 13.2 W h kg⁻¹ respectively. The enhancement of the electrochemical performance in the hybrid material is attributed to the pseudo capacitive nature of the metal oxide nanoparticles incorporated in the g-C₃N₄ matrix.