Probing the coupling of a dipole-bound electron with a molecular core

Abstract

A dipolar molecule can weakly bind an electron in a diffuse orbital. However, the spin–orbit coupling between this weakly bound electron and the electrons in the molecular core is not known. Here we probe this coupling using the linear C₂P⁻ anion with the ³Σ⁺ ground state, which possesses dipole-bound excited states because neutral C₂P (²Π) has a sufficiently large dipole moment. Photodetachment spectroscopy and resonant photoelectron spectroscopy are used to probe the nature of the dipole-bound states. Two dipole-bound excited states are observed with a binding energy of 37 cm⁻¹, corresponding to the two spin–orbit states of neutral C₂P (²Π_1/2 and ²Π_3/2). The current study demonstrates that the weakly bound electron in the dipole-bound excited states of C₂P⁻ is not spin-coupled to the electrons in the C₂P core and can be considered as a quasi-free electron.