Issue 46, 2020
From the journal:

Chemical Communications

Reversible control of ionic conductivity and viscoelasticity of organometallic ionic liquids by application of light and heat†

Ryo Sumitani,a   Hirofumi Yoshikawa ORCID logo b  and  Tomoyuki Mochida ORCID logo *ac  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai, Nada, Kobe, Hyogo 657-8501, Japan
E-mail: tmochida@platinum.kobe-u.ac.jp

b School of Science & Technology, Kwansei Gakuin University 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan

c Center for Membrane Technology, Kobe University, 1-1 Rokkodai, Nada, Kobe, Hyogo 657-8501, Japan

Abstract

Ru-containing ionic liquids [Ru(C5H5){C6H3(OC6H12CN)3}][N(SO2F)2] (1) and [Ru(C5H5){C6H5(OC3H6CN)}][N(SO2F)2] (2), having different numbers of substituents, were reversibly converted to coordination polymer solids and oligomeric liquids, respectively, by UV photoirradiation and heating. This feature enabled the control of their ionic conductivities and viscoelastic properties.

Graphical abstract: Reversible control of ionic conductivity and viscoelasticity of organometallic ionic liquids by application of light and heat

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Article information

DOI
https://doi.org/10.1039/D0CC02786C
Article type
Communication
Submitted
17 Apr 2020
Accepted
12 May 2020
First published
12 May 2020

Chem. Commun., 2020,56, 6189-6192

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Reversible control of ionic conductivity and viscoelasticity of organometallic ionic liquids by application of light and heat

R. Sumitani, H. Yoshikawa and T. Mochida, Chem. Commun., 2020, 56, 6189 DOI: 10.1039/D0CC02786C

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