Issue 53, 2020
From the journal:

Chemical Communications

Overriding ortho selectivity by template assisted meta-C–H activation of benzophenones†

Emanuele Casali, ORCID logo ‡a   Prakriti Kalra,‡b   Massimo Brochetta,a   Tania Borsari,a   Andrea Gandini,a   Tuhin Patra, ORCID logo *b   Giuseppe Zanoni ORCID logo *a  and  Debabrata Maiti ORCID logo *b  

* Corresponding authors

a Dipartimento di Chimica, Università di Pavia, Viale Taramelli 10, 27100 Pavia, Italy
E-mail: gz@unipv.it

b Department of Chemistry, IIT Bombay, Powai, Mumbai 400076, India
E-mail: tuhin.patra@uni-muenster.de, dmaiti@iitb.ac.in

Abstract

An orthogonal selectivity for distal meta-C–H activation of benzophenone is acheived by overriding the inherent proximal ortho-selectivity through a template assisted metalation approach. This strategy has been successfully utilized in Pd-catalyzed regioselective C–C and C–Si bond formation.

Graphical abstract: Overriding ortho selectivity by template assisted meta-C–H activation of benzophenones

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Article information

DOI
https://doi.org/10.1039/D0CC03172K
Article type
Communication
Submitted
02 May 2020
Accepted
19 May 2020
First published
20 May 2020

Chem. Commun., 2020,56, 7281-7284

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Overriding ortho selectivity by template assisted meta-C–H activation of benzophenones

E. Casali, P. Kalra, M. Brochetta, T. Borsari, A. Gandini, T. Patra, G. Zanoni and D. Maiti, Chem. Commun., 2020, 56, 7281 DOI: 10.1039/D0CC03172K

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