Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO2 capture

Zhaoqiang Zhang; Qi Ding; Shing Bo Peh; Dan Zhao; Jiyu Cui; Xili Cui; Huabin Xing

doi:10.1039/D0CC03196H

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Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO₂ capture†

Zhaoqiang Zhang,

^a Qi Ding,^a Shing Bo Peh,^b Dan Zhao,

^b Jiyu Cui,^a Xili Cui

*^a and Huabin Xing

Author affiliations

* Corresponding authors

^a Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
E-mail: cuixl@zju.edu.cn

^b Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, Singapore

Abstract

An ultramicroporous MOF, ZU-36-Ni (GeFSIX-3-Ni) is obtained for the first time via a mechanochemical-assisted approach. The material exhibits excellent performance for trace CO₂ capture (1.07 mmol g⁻¹ at 400 ppm) and benchmark 50/50 CO₂/CH₄ selectivity of 930, which is proven by dynamic breakthrough tests.

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Article information

DOI: https://doi.org/10.1039/D0CC03196H
Article type: Communication
Submitted: 04 May 2020
Accepted: 12 Jun 2020
First published: 13 Jun 2020

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Chem. Commun., 2020,56, 7726-7729

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Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO₂ capture

Z. Zhang, Q. Ding, S. B. Peh, D. Zhao, J. Cui, X. Cui and H. Xing, Chem. Commun., 2020, 56, 7726 DOI: 10.1039/D0CC03196H

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Chemical Communications