Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

Shohei Koyama; Tappei Tanabe; Shinya Takaishi; Masahiro Yamashita; Hiroaki Iguchi

doi:10.1039/D0CC03541F

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Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes†

Shohei Koyama,^a Tappei Tanabe,^a Shinya Takaishi,

^a Masahiro Yamashita^ab and Hiroaki Iguchi

*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi 980-8578, Japan
E-mail: h-iguchi@tohoku.ac.jp

^b School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

Abstract

Preliminary chemical reduction of naphthalenediimide (NDI)-based organic ligands was applied to the synthesis of a porous molecular conductor (PMC) with neutral metal nodes (cobalt(II) acetylacetonate). The obtained semiconductive PMC (PMC-2) was stable due to the neutral metal nodes, providing an advantage over electrochemical reduction.

This article is part of the themed collection: Functional Coordination Networks

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DOI: https://doi.org/10.1039/D0CC03541F
Article type: Communication
Submitted: 18 May 2020
Accepted: 23 Sep 2020
First published: 23 Sep 2020

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Chem. Commun., 2020,56, 13109-13112

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Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

S. Koyama, T. Tanabe, S. Takaishi, M. Yamashita and H. Iguchi, Chem. Commun., 2020, 56, 13109 DOI: 10.1039/D0CC03541F

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Chemical Communications

Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes†

Abstract

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Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

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