A 2D donor–acceptor covalent organic framework with charge transfer for supercapacitors†
Abstract
An electron donor–acceptor covalent organic framework (TTF-COF1) was constructed by the imine condensation of electron donor tetraformyl-tetrathiafulvalene (TTF-fo) and electron acceptor 2,6-diaminoanthraquinone (DAQ). TTF-COF1 has intramolecular charge transfer, offering capacitance of 752 F g−1 at 1 A g−1 and an energy density of 57 W h kg−1 at a power density of 858 W kg−1.