Issue 90, 2020
From the journal:

Chemical Communications

Monocarboxylate-driven structural growth in Calix[n]arene-polyoxotitanate hybrid systems: utility in hydrogen production from water†

Xin-Xue Yang,‡a   Wei-Dong Yu,‡b   Xiao-Yi Yi, ORCID logo *a   Lei-Jiao Li ORCID logo c  and  Chao Liu ORCID logo *a  

* Corresponding authors

a Hunan Provincial Key Laboratory of Chemical Power Sources, College of Chemistry and Chemical Engineering, Central South University, Changsha, P. R. China
E-mail: chaoliu@csu.edu.cn, xyyi@csu.edu.cn

b Hunan Institute of Nuclear Agricultural Science and Space Breeding, Hunan Academy of Agricultural Science, Changsha 410000, P. R. China

c Jilin Provincial Science and Technology Innovation Canter of Optical Materials and Chemistry, School of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun, Jilin 130022, China

Abstract

A carboxylate-driven assembly strategy has been developed for the first time to build calix[n]arene-based polyoxotitanate clusters with tuneable nuclearity and structures. Photocatalytic studies revealed that these clusters exhibit structural-dependent H2 evolution ability with a maximum rate up to 415.11 μmol h−1 g−1, which is almost the highest recorded in polyoxotitanate clusters.

Graphical abstract: Monocarboxylate-driven structural growth in Calix[n]arene-polyoxotitanate hybrid systems: utility in hydrogen production from water

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Article information

DOI
https://doi.org/10.1039/D0CC05336H
Article type
Communication
Submitted
05 Aug 2020
Accepted
15 Oct 2020
First published
15 Oct 2020

Chem. Commun., 2020,56, 14035-14038

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Monocarboxylate-driven structural growth in Calix[n]arene-polyoxotitanate hybrid systems: utility in hydrogen production from water

X. Yang, W. Yu, X. Yi, L. Li and C. Liu, Chem. Commun., 2020, 56, 14035 DOI: 10.1039/D0CC05336H

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