Issue 11, 2020
From the journal:

Dalton Transactions

Polyoxometalate-based room-temperature phosphorescent materials induced by anion–π interactions†

Xiao-Yuan Wu, ORCID logo a   Hai-Long Zhang, ORCID logo ab   Sa-Sa Wang, ORCID logo a   Weiming Wu,a   Lang Lin,c   Xiao-Yu Jiangc  and  Can-Zhong Lu ORCID logo *ab  

* Corresponding authors

a CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: czlu@fjirsm.ac.cn

b University of Chinese Academy of Sciences, Bejing 100049, China

c Fujian University of Technology, Fuzhou, Fujian 350108, PR China

Abstract

A series of host–guest materials containing polyoxometalate anions and lanthanide-organic layers have been synthesized and structurally characterized. By anion–π interactions between the anions and the π-acidic naphthalenediimide moieties, the materials emit strong red room-temperature phosphorescence and exhibit reversible photochromism.

Graphical abstract: Polyoxometalate-based room-temperature phosphorescent materials induced by anion–π interactions

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Article information

DOI
https://doi.org/10.1039/D0DT00159G
Article type
Communication
Submitted
15 Jan 2020
Accepted
20 Feb 2020
First published
21 Feb 2020

Dalton Trans., 2020,49, 3408-3412

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Polyoxometalate-based room-temperature phosphorescent materials induced by anion–π interactions

X. Wu, H. Zhang, S. Wang, W. Wu, L. Lin, X. Jiang and C. Lu, Dalton Trans., 2020, 49, 3408 DOI: 10.1039/D0DT00159G

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