Tunable thermal quenching properties of Na3Sc2(PO4)3:Eu2+ phosphors tailored by phase transformation details

Abstract

Luminescence thermal quenching of phosphors is one of the prominent problems in restricting their application in high-power LED devices. In the current work, tunable luminescence thermal quenching behaviors, including abnormal negative thermal quenching and normal thermal quenching, were demonstrated for Na₃Sc₂(PO₄)₃:Eu²⁺ phosphors tailored by phase transformation details. A series of ionic substitution schemes were employed to synthesize α-, β- and γ-Na₃Sc₂(PO₄)₃:Eu²⁺ phosphors, which show discrepant phase transformations during heating. The thermal event associated with phase transformation is perceived to be responsible for the observations of abnormal negative thermal quenching performances, in view of the suppression of non-radiative paths by consuming thermal energy during the phenomenon of phase transformation. Our results provide an insight into the relationship between the thermal quenching behaviors and phase transformation details of the Na₃Sc₂(PO₄)₃:Eu²⁺ phosphor and offer a useful clue to exploit high thermal stability phosphors.