Issue 26, 2020

Room temperature aqueous synthesis of UiO-66 derivatives via postsynthetic exchange

Abstract

Herein, we report the room temperature aqueous synthesis of the Zr(IV)-based metal–organic framework UiO-66 and a series of functionalized derivatives through postsynthetic exchange from a perfluorinated UiO-66-F4 precursor. All synthesized MOFs in this study were thoroughly characterized to verify formation of the desired MOF, porosity, crystallinity, and exchanged ligand content. This report represents a green, aqueous, room temperature synthesis of a highly valued series of Zr(IV)-based MOFs.

Graphical abstract: Room temperature aqueous synthesis of UiO-66 derivatives via postsynthetic exchange

Supplementary files

Article information

Article type
Communication
Submitted
29 May 2020
Accepted
17 Jun 2020
First published
18 Jun 2020

Dalton Trans., 2020,49, 8841-8845

Author version available

Room temperature aqueous synthesis of UiO-66 derivatives via postsynthetic exchange

M. Kalaj, K. E. Prosser and S. M. Cohen, Dalton Trans., 2020, 49, 8841 DOI: 10.1039/D0DT01939A

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