Issue 37, 2020
From the journal:

Dalton Transactions

Incorporation of coinage metal–NHC complexes into heptaphosphide clusters†

Minyoung Jo,a   Jingbai Li,b   Alina Dragulescu-Andrasi,a   Andrey Yu. Rogachev*b  and  Michael Shatruk ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA
E-mail: mshatruk@fsu.edu

b Department of Cnmhemistry, Illinois Institute of Technology, 3101 South Dearborn St, Chicago, IL 60616, USA
E-mail: arogache@iit.edu

Abstract

Cu(I) and Au(I) ions, capped with an N-heterocyclic carbene (NHC), react with (TMS)3P7 (TMS = trimethyl-silyl) to afford an η4-coordinated anion [NHCDippCu–P7(TMS)]− and a neutral trinuclear complex (NHCDippAu)3P7. Protecting the P7 cage with the TMS groups is instrumental in controlling the course of these reactions.

Graphical abstract: Incorporation of coinage metal–NHC complexes into heptaphosphide clusters

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Article information

DOI
https://doi.org/10.1039/D0DT03119D
Article type
Communication
Submitted
06 Sep 2020
Accepted
08 Sep 2020
First published
09 Sep 2020

Dalton Trans., 2020,49, 12955-12959

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Incorporation of coinage metal–NHC complexes into heptaphosphide clusters

M. Jo, J. Li, A. Dragulescu-Andrasi, A. Yu. Rogachev and M. Shatruk, Dalton Trans., 2020, 49, 12955 DOI: 10.1039/D0DT03119D

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