Issue 46, 2020
From the journal:

Dalton Transactions

One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]†

Simin Li,a   Kiyonori Takahashi, ORCID logo *ab   Ichiro Hisaki, ORCID logo c   Kenta Kokado ORCID logo abd  and  Takayoshi Nakamura*ab  

* Corresponding authors

a Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo 060-0810, Japan
E-mail: ktakahashi@es.hokudai.ac.jp, tnaka@es.hokudai.ac.jp

b Research Institute for Electronic Science (RIES), Hokkaido University, N20W10, Kita-ku, Sapporo, Japan

c Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka, Japan

d JST-PRESTO, Honcho 4–1-8, Kawaguchi, Saitama 332-0012, Japan

Abstract

Crystals of (HDABCO+)9(DABCO)[Ni(dmit)2]9·6CH3CN were shown to have a space group of R[3 with combining macron], a hexapetal flower-like channel of [Ni(dmit)2] anions, and a one-dimensional hydrogen bonding chain composed of protonated DABCO and CH3CN molecules. The crystals display antiferromagnetic and ferromagnetic interactions within and between hexamers, respectively, whereas the flexible DABCO-CH3CN array shows dielectric relaxation.

Graphical abstract: One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]

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Article information

DOI
https://doi.org/10.1039/D0DT03386C
Article type
Paper
Submitted
30 Sep 2020
Accepted
04 Nov 2020
First published
05 Nov 2020

Dalton Trans., 2020,49, 16772-16777

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One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]

S. Li, K. Takahashi, I. Hisaki, K. Kokado and T. Nakamura, Dalton Trans., 2020, 49, 16772 DOI: 10.1039/D0DT03386C

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