Issue 48, 2020
From the journal:

Dalton Transactions

Supersilyl as an effective monodentate ligand to stabilize four-coordinate manganese(ii) complexes†

Shogo Arata,a   Kosuke Suzuki, ORCID logo b   Kazuya Yamaguchi ORCID logo b  and  Yusuke Sunada ORCID logo *ac  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan

b Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

c Institute of Industrial Science, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan

Abstract

Supersilyl, –Si(SiMe3)3, serves as an effective ligand to afford a series of four-coordinate manganese(II) complexes. A dinuclear complex, [(THF)Mn{Si(SiMe3)3}(μ-Br)]2 (2), was readily synthesized by the reaction of MnBr2 with KSi(SiMe3)3. A subsequent ligand exchange of Br in 2 to –OtBu, methyl, or hydride afforded the corresponding manganese(II) complexes.

Graphical abstract: Supersilyl as an effective monodentate ligand to stabilize four-coordinate manganese(ii) complexes

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Article information

DOI
https://doi.org/10.1039/D0DT03837G
Article type
Communication
Submitted
07 Nov 2020
Accepted
01 Dec 2020
First published
09 Dec 2020

Dalton Trans., 2020,49, 17537-17541

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Supersilyl as an effective monodentate ligand to stabilize four-coordinate manganese(II) complexes

S. Arata, K. Suzuki, K. Yamaguchi and Y. Sunada, Dalton Trans., 2020, 49, 17537 DOI: 10.1039/D0DT03837G

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