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Catalytic decarboxylative reactions are attractive as biomimetic and environmentally friendly reaction processes. This review summarizes the recent results of organocatalytic enantioselective decarboxylative reactions of malonic acid half oxy- or thioesters, β-ketoacids, and related compounds from October 2013 to December 2019.

Graphical abstract: Catalytic enantioselective decarboxylative nucleophilic addition reactions using chiral organocatalysts

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