A [Pd2L4]4+ cage complex for n-octyl-β-D-glycoside recognition

Xander Schaapkens; Eduard O. Bobylev; Joost N. H. Reek; Tiddo J. Mooibroek

doi:10.1039/D0OB01081B

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A [Pd₂L₄]⁴⁺ cage complex for n-octyl-β-d-glycoside recognition†

Xander Schaapkens,^a Eduard O. Bobylev,^a Joost N. H. Reek

^a and Tiddo J. Mooibroek

*^a

Author affiliations

* Corresponding authors

^a Van ‘t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands
E-mail: t.j.mooibroek@uva.nl

Abstract

The cage complex [Pd₂9₄]⁴⁺ (3′) binds n-octyl glycosides in DCM/DMSO (9 : 1) solution with K_a ≈ 51 M⁻¹ for n-Oct-β-D-Glc and K_a ≈ 29 M⁻¹ for n-Oct-β-D-Gal.

This article is part of the themed collection: Chemical Biology in OBC

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Article information

DOI: https://doi.org/10.1039/D0OB01081B
Article type: Communication
Submitted: 25 May 2020
Accepted: 09 Jun 2020
First published: 09 Jun 2020
This article is Open Access

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Org. Biomol. Chem., 2020,18, 4734-4738

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A [Pd₂L₄]⁴⁺ cage complex for n-octyl-β-D-glycoside recognition

X. Schaapkens, E. O. Bobylev, J. N. H. Reek and T. J. Mooibroek, Org. Biomol. Chem., 2020, 18, 4734 DOI: 10.1039/D0OB01081B

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Organic & Biomolecular Chemistry