A novel strategy has been developed for the synthesis of indole fused spiro-1,4-diazocane derivatives. Using a tandem Prins cyclization, this is the first report on the synthesis of eight-membered spirodiazocane scaffolds, which are less accessible due to ring strain but more relevant to drug discovery.
C. Rapelli, B. Sridhar and B. V. Subba Reddy, Org. Biomol. Chem., 2020, 18, 6710 DOI: 10.1039/D0OB01384F
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