Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al4F6

Ying-ying Xue; Ying Zhang; Zhong-hua Cui; Yi-hong Ding

doi:10.1039/D0RA02280B

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Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al₄F₆†

Ying-ying Xue,^a Ying Zhang,^a Zhong-hua Cui

*^b and Yi-hong Ding

*^ac

Author affiliations

* Corresponding authors

^a Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023, P. R. China
E-mail: yhdd@jlu.edu.cn

^b Institute of Atomic and Molecular Physics, Jilin University, Changchun 130023, P. R. China
E-mail: zcui@jlu.edu.cn

^c Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China

Abstract

For over 100 years, known bent C [triple bond, length as m-dash] C compounds have been limited to those with organic (I) and all-carbon (II) scaffoldings. Here, we computationally report a novel type (III) of bent CC compound, i.e., C₂Al₄F₆-01, which is the energetically global minimum isomer and bears an inorganic–metallic scaffolding and unexpected click reactivity.

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Article information

DOI: https://doi.org/10.1039/D0RA02280B
Article type: Paper
Submitted: 11 Mar 2020
Accepted: 16 Jun 2020
First published: 03 Jul 2020
This article is Open Access

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RSC Adv., 2020,10, 25275-25280

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Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al₄F₆

Y. Xue, Y. Zhang, Z. Cui and Y. Ding, RSC Adv., 2020, 10, 25275 DOI: 10.1039/D0RA02280B

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