Issue 25, 2020, Issue in Progress
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RSC Advances

The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them†

Sandeep Kumar Dey*a  and  Christoph Janiak ORCID logo *b  

* Corresponding authors

a School of Chemical Sciences, Goa University, Taleigao Plateau, Goa 403206, India
E-mail: sandeepdey@unigoa.ac.in
Tel: +91-7387633550

b Institute for Inorganic and Structural Chemistry, Heinrich-Heine University Düsseldorf, 40225 Düsseldorf, Germany
E-mail: janiak@uni-duesseldorf.de
Tel: +49-2118112286

Abstract

Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene compounds (SL and CL1–3) based on 1H-NMR, 19F-NMR, LC-MS and UV-vis spectroscopy experiments.

Graphical abstract: The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them

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Article information

DOI
https://doi.org/10.1039/D0RA02293D
Article type
Paper
Submitted
11 Mar 2020
Accepted
03 Apr 2020
First published
14 Apr 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 14689-14693

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The curious case of salicylidene-based fluoride sensors: chemosensors or chemodosimeters or none of them

S. K. Dey and C. Janiak, RSC Adv., 2020, 10, 14689 DOI: 10.1039/D0RA02293D

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