Dispersion of arc-discharged single-walled carbon nanotubes using the natural α-amino acid derivative N-dodecanoyl leucinate

Abstract

The natural α-amino acid derivate N-dodecanoyl leucinate was synthesized via Schotten–Baumann reaction and alkali treatment, and was applied to the dispersion of arc-discharged single-walled carbon nanotubes (SWNTs). Optical absorption and Raman scattering spectra as well as AFM observation confirmed the effective individualization and selective dispersion of SWNTs. Moreover, charge transfer from N-dodecanoyl leucinate to SWNTs was evidenced by FT-IR and Raman scattering spectroscopic analyses. We believe that the formation of a charge transfer complex between dispersants and SWNTs is responsible for the effective individualization of SWNTs, and that the charge transfer from dispersants to SWNTs (or from SWNTs to dispersants) is crucial for selective dispersion of semiconducting (or metallic) SWNTs.