Self-assembly of amphiphilic poly(styrene-b-acrylic acid) on magnetic latex particles and their application as a reusable scale inhibitor

Abstract

The deposition of scale on membranes or container and pipe surfaces (clogging the system) is a costly issue in water treatment processes or water-cooling systems. To effectively cope with this issue, magnetic polymeric nanoparticles (MPNPs) have been developed and applied as promising scale inhibitors, due to their high surface-area-to-volume ratio, surface modifiability, and magnetic separation ability. Carboxylated MPNPs, having a monodisperse size distribution (236 ± 26 nm) with a high magnetic content of 70 wt% and superparamagnetic properties, were fabricated by using a 2-step process: (i) formation of clusters of hydrophobic magnetic nanoparticles stabilized by oleic acid (OA-MNPs), and (ii) self-assembly of the amphiphilic block copolymer of poly(styrene₂₇-b-acrylic acid₁₂₀) (PS₂₇-b-PAA₁₂₀) onto the cluster surfaces. With application of ultrasonication to 12.0 wt% OA-MNPs, a three-dimensional network was formed by particle–particle interactions, suppressing coalescence, and then creating stable magnetic clusters. The cluster surfaces were then adsorbed by amphiphilic PS₂₇-b-PAA₁₂₀ via the attractive force between hydrophobic PS blocks. This moves longer hydrophilic PAA blocks containing carboxylic acid groups into the water phase. The formulated MPNPs acted as a nanosorbent for calcium ion (Ca²⁺) removal with a removal efficiency of 92%. The MPNPs can be effectively reused for up to 4 cycles. Based on the electrostatic interactions between the negatively-charged polymer and the hydrated Ca²⁺, the resulting precipitation leads to the prevention of calcium carbonate scale formation. Insights into this mechanism open up a new perspective for magnetic-material applications as effective antiscalants.