Suppressing loss tangent with significantly enhanced dielectric permittivity of poly(vinylidene fluoride) by filling with Au–Na1/2Y1/2Cu3Ti4O12 hybrid particles

Abstract

Three-phase gold nanoparticle–Na_1/2Y_1/2Cu₃Ti₄O₁₂ (Au–NYCTO)/poly(vinylidene fluoride) (PVDF) composites with 0.095–0.487 hybrid particle volume fractions (f) were fabricated. Au nanoparticles with a diameter of ∼10 nm were decorated on the surfaces of high-permittivity NYCTO particles using a modified Turkevich's method. The polar β-PVDF phase was confirmed to exist in the composites. Significantly enhanced dielectric permittivity of ∼98 (at 1 kHz) was obtained in the Au–NYCTO/PVDF composite with f_Au–NYCTO = 0.487, while the loss tangent was suppressed to 0.09. Abrupt changes in the dielectric and electrical properties, which signified percolation behavior, were not observed even when f_Au–NYCTO = 0.487. Using the effective medium percolation theory model, the percolation threshold (f_c) was predicted to be at f_Au–NYCTO = 0.69, at which f_Au was estimated to ∼0.19 and close to the theoretical f_c value for the conductor–insulator composites (f_c = 0.16). A largely enhanced dielectric response in the Au–NYCTO/PVDF composites was contributed by the interfacial polarization effect and a high permittivity of the NYCTO ceramic filler. Au nanoparticles can produce the local electric field in the composites, making the dipole moments in the β-PVDF phase and NYCTO particles align with the direction of the electric field.