Issue 9, 2020

Controllable fabrication of α-Ni(OH)2 thin films with preheating treatment for long-term stable electrochromic and energy storage applications

Abstract

Although dual-functional electrochromic energy storage (EES) materials are important for the development of smart windows for energy-saving applications, few EES materials simultaneously possess fast switching time, long-term stability and high capacitance, which are among the most important characteristics for their applications. Herein, we present the controllable synthesis of pure α-Ni(OH)2via an improved one-step electrodeposition process. The as-deposited Ni(OH)2 EES electrodes exhibited significantly enhanced performances with broad-range optical modulation of 78.6% at 550 nm, fast switching time of 0.9 s for coloration and 1.2 s for bleaching, as well as excellent stability (>5000 cycles). Meanwhile, the EES electrodes exhibited an excellent energy storage performance with an areal capacitance of 154.05 mF cm−2, and could light up a green light-emitting diode for 20 min. The improved EES performance is mainly attributed to the phase-controllable fabrication of uniform and compact α-Ni(OH)2 thin films with a small charge-transfer resistance, which exhibit a stable structure, allowing for fast ion intercalation/de-intercalation during the reversible redox reactions. The scalable and cost-effective fabrication of α-Ni(OH)2 materials is expected to expand the EES applications to other metal hydroxide materials.

Graphical abstract: Controllable fabrication of α-Ni(OH)2 thin films with preheating treatment for long-term stable electrochromic and energy storage applications

Supplementary files

Article information

Article type
Paper
Submitted
19 Nov 2019
Accepted
13 Jan 2020
First published
16 Jan 2020

J. Mater. Chem. C, 2020,8, 3010-3016

Controllable fabrication of α-Ni(OH)2 thin films with preheating treatment for long-term stable electrochromic and energy storage applications

C. Su, M. Qiu, Y. An, S. Sun, C. Zhao and W. Mai, J. Mater. Chem. C, 2020, 8, 3010 DOI: 10.1039/C9TC06354D

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