[Bi6Mo3(CO)9]4−: a multiple local σ-aromatic cluster containing a distorted Bi6 triangular prism

Lei Qiao; Dandan Chen; Jun Zhu; Alvaro Muñoz-Castro; Zhong-Ming Sun

doi:10.1039/D1CC00734C

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[Bi₆Mo₃(CO)₉]⁴⁻: a multiple local σ-aromatic cluster containing a distorted Bi₆ triangular prism†

Lei Qiao,^a Dandan Chen,^b Jun Zhu,

^b Alvaro Muñoz-Castro^c and Zhong-Ming Sun

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Elemento-Organic Chemistry, Tianjin Key Lab of Rare Earth Materials and Applications, School of Material Science and Engineering, Nankai University, Tianjin 300350, China
E-mail: sunlab@nankai.edu.cn

^b State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

^c Grupo de Química Inorgánicay Materiales Moleculares, Facultad de Ingenieria, Universidad Autonoma de Chile, El Llano Subercaseaux, Santiago 2801, Chile

Abstract

The first Zintl cluster containing a distorted Bi₆ triangular prism, [Bi₆Mo₃(CO)₉]⁴⁻, has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features multiple local σ-aromaticity.

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Article information

DOI: https://doi.org/10.1039/D1CC00734C
Article type: Communication
Submitted: 08 Feb 2021
Accepted: 08 Mar 2021
First published: 08 Mar 2021

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Chem. Commun., 2021,57, 3656-3659

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[Bi₆Mo₃(CO)₉]⁴⁻: a multiple local σ-aromatic cluster containing a distorted Bi₆ triangular prism

L. Qiao, D. Chen, J. Zhu, A. Muñoz-Castro and Z. Sun, Chem. Commun., 2021, 57, 3656 DOI: 10.1039/D1CC00734C

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Chemical Communications