Retracted Article: Nucleophilic iodonium interactions (NIIs) in 2-coordinate iodine(i) and silver(i) complexes

Abstract

The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(I) and iodonium (I⁺) complexes and studying their ¹⁵N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(I) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.