Issue 58, 2021
From the journal:

Chemical Communications

Rh-catalyzed tunable defluorinative borylation†

Fei Hao, ORCID logo ab   Xueyun Shang,a   Zhenwei Liu,a   He Zhang,*b   Jin-Hong Lin ORCID logo *bc  and  Ji-Chang Xiao ORCID logo *b  

* Corresponding authors

a Shandong Provincial Key Laboratory of Molecular Engineering, Qilu University of Technology-Shandong Academy of Science, Ji’nan 250353, China

b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: zhanghe07@gmail.com, jlin@sioc.ac.cn, jchxiao@sioc.ac.cn

c Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, P. R. China
E-mail: jlin@shu.edu.cn

Abstract

Described herein is a Rh-catalyzed tunable defluorinative borylation of allylic gem-difluorides to provide allylborylated monofluoroalkenes or homoallylborylated monofluoroalkenes with excellent Z/E selectivities. Completely different reaction paths were observed by slightly changing the reaction conditions. Allylborylated monofluoroalkenes were further converted into dihydroxyl-containing monofluoroalkenes.

Graphical abstract: Rh-catalyzed tunable defluorinative borylation

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Article information

DOI
https://doi.org/10.1039/D1CC02079J
Article type
Communication
Submitted
19 Apr 2021
Accepted
17 Jun 2021
First published
17 Jun 2021

Chem. Commun., 2021,57, 7124-7127

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Rh-catalyzed tunable defluorinative borylation

F. Hao, X. Shang, Z. Liu, H. Zhang, J. Lin and J. Xiao, Chem. Commun., 2021, 57, 7124 DOI: 10.1039/D1CC02079J

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