Issue 59, 2021

Photoreductive chlorine elimination from a Ni(iii)Cl2 complex supported by a tetradentate pyridinophane ligand

Abstract

Herein we report the isolation, characterization, and photoreactivity of a stable NiIII dichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state. Subsequently, the NiIIICl2 species can be regenerated via a reaction with PhICl2.

Graphical abstract: Photoreductive chlorine elimination from a Ni(iii)Cl2 complex supported by a tetradentate pyridinophane ligand

Supplementary files

Article information

Article type
Communication
Submitted
21 Apr 2021
Accepted
24 Jun 2021
First published
25 Jun 2021

Chem. Commun., 2021,57, 7264-7267

Author version available

Photoreductive chlorine elimination from a Ni(III)Cl2 complex supported by a tetradentate pyridinophane ligand

H. Na, M. B. Watson, F. Tang, N. P. Rath and L. M. Mirica, Chem. Commun., 2021, 57, 7264 DOI: 10.1039/D1CC02114A

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